Adsorption of n-Pentane on Mesoporous Silica and Adsorbent Deformation
نویسندگان
چکیده
منابع مشابه
Adsorption of n-pentane on mesoporous silica and adsorbent deformation.
Development of quantitative theory of adsorption-induced deformation is important, e.g., for enhanced coalbed methane recovery by CO2 injection. It is also promising for the interpretation of experimental measurements of elastic properties of porous solids. We study deformation of mesoporous silica by n-pentane adsorption. The shape of experimental strain isotherms for this system differs from ...
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The Derjaguin-Broekhoff-de Boer theory of capillary condensation is employed to describe deformation of mesoporous solids in the course of adsorption-desorption hysteretic cycles. We suggest a thermodynamic model, which relates the mechanical stress induced by the adsorbed phase to the adsorption isotherm. Analytical expressions are derived for the dependence of the solvation pressure on the va...
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The goal of this work is to understand adsorption-induced deformation of hierarchically structured porous silica exhibiting well-defined cylindrical mesopores. For this purpose, we performed an in situ dilatometry measurement on a calcined and sintered monolithic silica sample during the adsorption of N2 at 77 K. To analyze the experimental data, we extended the adsorption stress model to accou...
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ژورنال
عنوان ژورنال: Langmuir
سال: 2013
ISSN: 0743-7463,1520-5827
DOI: 10.1021/la401513n